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Mysterious obsidian in a basaltic eruption?!

30 Apr 2020 by VIPS Commission

Annabelle Foster – Durham University


The mystery of oozing, fluidal obsidian pyroclasts co-erupting with scoria from a basaltic fissure-eruption, Ascension Island, South Atlantic.

Basaltic eruptions are the most common manifestations of volcanism on Earth. Pyroclasts help volcanologists unravel the timeline of magma storage and ascent prior to eruptions and vent processes during eruptions, which in turn contributes to hazard mitigation models associated with impending volcanic eruptions.

A recent field excursion to Ascension Island uncovered unique and highly unusual obsidian pyroclasts which co-erupted with scoria in a dominantly basaltic fissure eruption. They comprise of dense glassy bombs which range in size from millimeter spherical beads to large spatter-like bombs (>40 cm in diameter). The obsidian clasts show fluidal shapes (such as suspended drops, large outflows and stretched filaments) which imply that they erupted with unusually low melt viscosities and landed hot on chilled scoria clasts.

Figure 1: Photographs (taken by Rich Brown) of the obsidian pyroclasts found within scoria ramparts. (A) Tongue-like pyroclast that flowed on impact. (B) Broken glass filaments with thin glass bridging between them. (C) Larger glassy pyroclast that has undergone considerable post-impact flow. (D) Glass droplet frozen onto the side of a scoria clast on the fissure edge.
Figure 2: Photographs of the obsidian pyroclasts. (A) Example of the base of a typical pyroclast which contains scoria and lithic clasts. (B) Cut section showing how the glass has flowed internally and interacted with the scoria as it landed. (C) Cuboid glassy clast with near parallel sides (shaped like a chocolate – but again not edible!). (D) Spherical glass drop stuck to the exterior of the scoria clast. (E) A smaller feature of photograph A; delicate thin filaments bridging a narrow crack in the exterior of the sample. (F) Bubbles in the glass which follow the edge of scoria clasts.

In-situ geochemical analyses on the obsidian and scoria glass (using electron microprobe) confirms two distinct magmas; the obsidian is rhyolitic, while the scoria is dominantly trachy-andesite. The magmatic compositions are bimodal, with clear separation between the obsidian and scoria components which is exemplified in differing macrocryst species present in the two pyroclasts.

Figure 3a: Total alkali vs. Silica plot showing two distinct compositions of the obsidian (rhyolite) and scoria (dominantly trachy-andesite). Figure 3b: Ternary feldspar compositional plot of obsidian and scoria macrocrysts.

The obsidian clasts only account for a small-volume of the total ejected material. This, coupled with the distinct magmatic compositions, suggests that the two magmas did not reside together in a density stratified magma chamber. An alternative possibility is that a shallow pocket of degassed rhyolitic magma was intersected by ascending mafic magma in dike. However, this also does not account for the low volume of eruption obsidian and absence of mixing/mingling textures. This is comparable in the wider Ascension Island magmatic suite where there is no evidence for magma mixing. Therefore, the storage of the two magmas and fragmentation at the subsurface remains ambiguous.

Figure 4: Schematic diagram of fissure (red) through felsic lavas (yellow) on Ascension Island. At t1, surrounding country rock (felsic lavas) are ripped from the conduit margins. They are entrained within the fire fountain at t2, and by t3 have likely outgassed, losing the majority of exsolved volatiles. On deposition (t4) the magma remained hot and flowed through pore spaces within the underlying scoria.

Currently, the preferred hypothesis for their origin is assimilation of water-/gas-poor felsic country rock, which bypassed the mafic eruption and remained in isolation until deposition. Reheating to the basaltic temperatures of the mafic dike would exceed the glass-transition temperature, remobilising the clasts, thus invoking highly fluidal textures. However, similar pyroclasts elsewhere that co-erupted with basalt have examples of large rhyolitic inclusions which show no evidence of re-melting. Ascension lacks any intermediate clast-type, which highlights the unusual nature of these pyroclasts.

Yellow gold background texture

The origin of these obsidian pyroclasts would benefit from future field excursions to Ascension Island, to look closely at the visible conduit and potentially uncover more pyroclasts which show a range in melting regimes. Additionally, obtaining water contents in the obsidian would provide insights into the magmatic processes (melting, crystallisation and assimilation), further placing constrains on their genesis.

Special thanks to Rich Brown, Katy Chamberlain, Fabian Wadsworth and Kate Dobson for insightful conversations and help during the supervision of this project.


Annabelle Foster (annabelle.foster@durham.ac.uk) is in the first year of her doctoral studies at Durham University (United Kingdom), after completing a masters by research. Currently, Annabelle looks at obsidian textures, stable isotopes and uses major element geochemistry to reconstruct the range of physical processes controlling degassing at silicic volcanoes. The project is supervised by Fabian Wadsworth, Madeleine Humphreys (Durham University), Dan Barfod (Glasgow, SUERC) and Hugh Tuffen (Lancaster University).

Annabelle also runs an Instagram geology blog (@Geology-talk) where she shares bite-sized pieces of geology, geo-art and her ongoing research. You can follow her on twitter too (@Volcannabelle)!

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